Volume 473
Main Index

Issues 1-2, Pages 1-369 (28 June 1994)

Preface Page IX Hiroshi Yamazaki

Organometallic chemistry in Japan — how it has developed Pages XI-XVII Akio Yamamoto

Subject index of volume 473 Pages C5-C12

Author index of volume 473 Pages C3-C4

Studies on organosilicon chemistry : CXXII. Reaction of 2-oxiranylallylsilanes with acetals. Direct introduction of a vinyloxirane moiety Pages C1-C2 Makoto Hojo, Naruyasu Ishibashi, Katsufumi Ohsumi, Katsukiyo Miura, Akira Hosomi

Towards novel organic synthesis on multimetallic centres: Syntheses and reactivities of dinuclear ruthenium thiolate complexes Pages 1-14 Masanobu Hidai, Yasushi Mizobe, Hiroyuki Matsuzaka

Silicon-carbon unsaturated compounds. : XLVIII. Synthesis and reactions of silicon analogs of lithium enolates Pages 15-17 Joji Ohshita, Yoshiteru Masaoka, Shin Masaoka, Mitsuo Ishikawa, Akitomo Tachibana, Tasuku Yano and, Tokio Yamabe

Molecular structures and charge-transfer complexes of cis-dibenzo[c,h]-1,6-disilabicyclo[4.4.0]deca-3,8-dienes and bi(benzo[c]silacyclopent-3-ene-1-yl)s Pages 19-27 Soichiro Kyushin, Masanobu Ikarugi, Satoshi Tsunakawa, Yukiko Izumi, Michihiro Miyake, Mitsuo Sato, Hideyuki Matsumoto, Midori Goto

Electronic spectra of (amino)(phenyl)disilanes Pages 29-34 Kohei Tamao, Atsushi Kawachi, Yoshiki Nakagawa, Yoshihiko Ito

Photochemical carbon-silicon bond forming reaction on electron-deficient alkenes by disilanes and polysilanes via photoinduced electron transfer Pages 35-43 Kazuhiko Mizuno, Kazuhisa Nakanishi, Jun-ichi Chosa, Yoshio Otsuji

Synthesis, absorption characteristics and some reactions of polygermanes Pages 45-54 Kunio Mochida, Hiromi Chiba

Mechanistic insight into the cinnamylmetal-thioacetal reaction employing 2-acetoxy-2-phenylacetaldehyde monothioacetal Pages 55-62 Tsuneo Sato, Junzo Otera

Diversity in the reaction modes of anionic and cationic stannyl reagents: γ-Chloro allylstannanes as a vinyl carbene equivalent, and its application for (±) -bakuchiol synthesis Pages 63-70 Jun Fujiwara, Tadashi Sato

Generation of allyl- and benzyllithiums from the corresponding halides by the aid of lithium-tellurium exchange reactions Pages 71-83 Takahiro Kanda, Shinzi Kato, Takushi Sugino, Nobuaki Kambe and, Noboru Sonoda

A new convenient preparation of monocyclooctatetraenyl-lanthanide complexes from metallic lanthanides and oxidants Pages 85-91 Kazushi Mashima, Yuushou Nakayama, Akira Nakamura, Nobuko Kanehisa and, Yasushi Kai, Hidemasa Takaya

Carbon-carbon bond forming reactions via new organosamarium(III) intermediates Pages 93-99 Masahiro Murakami, Yoshihiko Ito

Synthesis and X-ray structure of the divalent and trivalent ytterbium-molybdenum complexes YbII(HMPA)4(μ-OCMo(CO)2CP)2 and [YbIII(HMPA)5(μ-OCMo(CO)2Cp)][CpMo(CO)3]2· THF Pages 101-104 Zhaomin Hou, Ken-ichi Aida, Yuzuru Takagi, Yasuo Wakatsuki

Reaction courses for formation of early transition metal phenoxides Pages 105-116 Hajime Yasuda, Yuushou Nakayama, Kazuo Takei, Akira Nakamura, Yasushi Kai, Nobuko Kanehisa

Highly regioselective reaction of zirconocene-alkene complexes with aldehydes or ketones Pages 117-128 Noriyuki Suzuki, Christophe J. Rousset, Koichiro Aoyagi, Martin Kotora, Tamotsu Takahashi, Maki Hasegawa, Yu Nitto and, Masahiko Saburi

Catalytic asymmetric induction of planar chirality: Palladium-catalyzed asymmetric cross-coupling of meso tricarbonyl(arene) chromium complexes with alkenyl- and arylboronic acids Pages 129-137 Motokazu Uemura, Hikaru Nishimura, Tamio Hayashi

Synthesis and reactivity of platinum-containing heterodinuclear complexes with methyl and 1,2-bis(diphenylphosphino)ethane ligands. X-Ray crystal structure of (dpe) MePt---FeCp(CO)2 · THF Pages 139-147 Atsushi Fukuoka, Takanori Sadashima, Takeshi Sugiura, Xiaosong Wu, Yuji Mizuho, Sanshiro Komiya

Preparation and some reactions of bis(η5-cyclopentadienyl)hydrido(tosylato)-molybdenum and -tungsten Pages 149-154 Makoto Minato, Jian-Guo Ren, Hideshi Tomita, Tadayuki Tokunaga, Fumihiro Suzuki, Tadashi Igarashi, Takashi Ito

Preparation and structure of the first ansa-molybdenocene and tungstenocene derivatives. Reaction of [O(SiMe2C5H4)2]MoH2 with methyl methacrylate to probe the olefin attacking site Pages 155-162 Takaya Mise, Mami Maeda, Takayuki Nakajima, Kimiko Kobayashi, Isao Shimizu, Yasuhiro Yamamoto, Yasuo Wakatsuki

Photo-, electro-, and thermal carbonylation of alkyl iodides in the presence of group 7 and 8–10 metal carbonyl catalysts Pages 163-173 Teruyuki Kondo, Yoshitsugu Sone, Yasushi Tsuji, Yoshihisa Watanabe

Unusual reactivities of (μ-η2:η2-FP---CC---H)Co2(CO)6, the adducts of FP---CC---H to Co2(CO)8: photolysis, thermolysis and reduction with hydrosilanes giving polynuclear complexes, (CP)2Fe2Co3(μ5-C=CH)(CO)10, (μ-CH=CH)[(−μ3-C)Co3(CO)9]2 and CpFeCo3(μ-C=CH2)(CO)9 Pages 175-186 Munetaka Akita, Masako Terada, Naomi Ishii, Hideki Hirakawa, Yoshihiko Moro-oka

Reactions of sterically congested secondary silanes with iron carbonyls. Formation of μ-silylene complexes Fe2(CO)8(μ-SiR2) (R = mesityl and O(2,6-iPr2C6H3)) Pages 187-193 Hiromi Tobita, Isao Shinagawa, Setsuko Ohnuki, Machiko Abe, Hiroshi Izumi, Hiroshi Ogino

Preparation and characterization of μ-alkyne-hexacarbonyldicobalt complexes derived from 1,1′-dialkynylferrocene. Molecular structures of {(η5-C5H4=CPh)2Fe}{Co2(CO)6}2 and {(η5--C5H4CCPh)2Fe} Co2(CO)6 Pages 195-204 Kiyotaka Onitsuka, Xin-Qung Tao, Wen-Qing Wang, Yasuhiro Otsuka, Kenkichi Sonogashira, Tomohiro Adachi and, Toshikatsu Yoshida

Syntheses and reactivities of ferrocenyl organyl tellurides Pages 205-213 Yoshiaki Nishibayashi, Takashi Chiba, Jai Deo Singh, Sakae Uemura, Shin-ichi Fukuzawa

Conjugate addition of allylic groups to α,β-unsaturated carbonyl compounds via (η3-allyl)Fe(CO)2NO complexes Pages 215-224 Keiji Itoh, Saburo Nakanishi, Yoshio Otsuji

Ruthenium(II) hydrido complexes of quadridentate crown thioethers, trans-RuH(Cl)(syn-L) (L = Me4[14]aneS4, Me6[15]aneS4, Me8[16]aneS4) and {Ru2H(μ-H)Cl(syn-Me4[14]aneS4)2} Cl containing a linear Ru---H---Ru bond. Novel characteristics of syn-crown thioethers affecting discrimination of axial ligands and geometry of the unsupported Ru---HW---Ru linkage Pages 225-241 Toshikatsu Yoshida, Tomohiro Adachi, Tatsuo Ueda, Fumitaka Goto, Katsumi Baba, Toshihiro Tanaka

Synthesis by the Arbuzov-like dealkylation reaction, characterization, and reactivity of phosphonate and amino-substituted phosphonate ruthenium complexes, [(η5-C5H5)(CO)2Ru{P(O)(OR)n(NC4H8) 2−n}] (n = 0–2), and comparison with the iron analogues Pages 243-252 Hiroshi Nakazawa, Toshiyuki Fujita, Kazuyuki Kubo, Katsuhiko Miyoshi

Reaction rate enhancement by addition of anionic surfactant SDS in the ruthenium catalyzed hydrogen transfer from a 1,4-diol to 4-phenyl-3-buten-2-one Pages 253-256 Kyoko Nozaki, Masanori Yoshida, Hidemasa Takaya

Ruthenium-catalysed reductive cleavage of allylic esters with formic acid and triethylamine. Application to short-step synthesis of α-hydroxy acids Pages 257-264 Yooichiroh Maruyama, Takao Sezaki, Masafumi Tekawa, Toshiaki Sakamoto, Isao Shimizu, Akio Yamamoto

Reaction of RuH2(PMe3)4 with benzaldehyde. Formation of novel oxametallacycle and metallacycloketone complexes via C---H bond activation of aldehyde Pages 265-272 Fumiyuki Ozawa, Isao Yamagami, Akio Yamamoto

Hexaruthenium carbido carbonyl methyl cluster [PPN][Ru6C(CO)16(CH3)] as catalyst precursor for hydrogenation of olefins. Syntheses and structures of unsaturated and saturated hexaruthenium hydrido clusters [PPN][Ru6C(CO)15H] and [PPN][Ru6C(CO)16H] Pages 273-284 T. Chihara, H. Yamazaki

Interconversion between (C5R5) RuIV(allyl) and (C5R5) RuII(diene) complexes Pages 285-294 Katsuyuki Masuda, Mikio Saitoh, Katsuyuki Aoki, Kenji Itoh

Carbon-carbon bond cleavage and skeletal rearrangement of coordinated norbornadiene. Preparation of a η6-6-methylfulvene complex [(C5Me5)Ru(C5H4CHCH3)]BF4 Pages 295-301 Hiroharu Suzuki, Takeaki Kakigano, Hideno Fukui, Masako Tanaka, Yoshihiko Moro-oka

Synthesis and structure of planar-chiral (1,2,4-trisubstituted cyclopentadienyl) cobalt(tetraarylcyclobutadiene) complexes containing three different chiralities in one molecule Pages 303-311 Mitsunari Uno, Katsuhiro Ando, Nobuko Komatsuzaki, Takehiro Tsuda, Takanori Tanaka, Masami Sawada, Shigetoshi Takahashi

A novel metallacycle, 1,2,5,3-cobaltadithiazole. Formation, structure, and properties of (η5-cyclopentadienyl or η5 pentamethylcyclopentadienyl)(1-phenylmethanimine-N,1l-dithiolato) - cobalt(III) Pages 313-321 Akihiro Kato, Masaki Tono, Naoki Hisamatsu, Sho-hei Nozawa, Kazuo Ninomiya, Toru Sugiyama, Masatsugu Kajitani, Takeo Akiyama, Akira Sugimori

Carbene insertion into oxygen---hydrogen bonds by metalloporphyrin catalysts Pages 323-327 Takashi Hayashi, Tomoki Kato, Tomomasa Kaneko, Tomohito Asai, Hisanobu Ogoshi

Palladium(II) and/or copper(II)-catalyzed carboxylation of small alkanes such as methane and ethane with carbon monoxide Pages 329-334 Kazuyuki Nakata, Yoshinori Yamaoka, Tsutomu Miyata, Yuki Taniguchi, Ken Takaki, Yuzo Fujiwara

Preparation of vinylgermanes and a germole by the Pd-catalyzed reactions of Me(in3)GeCn with acetylenes Pages 335-342 Naoto Chatani, Tsumoru Morimoto, Toyoshige Muto, Shinji Murai

Palladium-catalyzed hydrogenolysis of 2-alkynyl formates and elimination of 2-alkynyl carbonates. 2-Alkynylpalladium complex vs. allenylpalladium complex as intermediates Pages 343-352 Tadakatsu Mandai, Takaji Matsumoto, Yoshikazu Tsujiguchi, Shin Matsuoka, Jiro Tsuji

Selective sp3 C---H bond activation of alkylaromatics promoted by platinum complexes Pages 353-358 Akira Miyashita, Masatoshi Hotta, Yoshiko Saida

Mono- and dinuclear alkoxide copper complexes with PPh3 ligands Pages 359-369 Kohtaro Osakada, Tadashi Takizawa, Masako Tanaka, Takakazu Yamamoto